Programme Content
This Module covers the basics of electrochemistry and how to use it to understand the batteries. Some analogy from commonly known examples will be used to introduce the advanced concepts like over potential and associated energy loss in batteries, which leads to thermal runaway situations. Besides, the phenomenon responsible for energy storage, such as intercalation, alloying and conversion will be discussed with examples of anode and cathode materials used in the current state of the art Li-ion battery. Besides electrical characterisation pertain to the anode, cathode and whole cell would be discussed in details, particularly non-destructive techniques to understand the state of health and state of charge of battery.
Prof. Kothandaraman Ramanujam, Department of Chemistry, IIT Madras.
Electrochemical cells (a) Converting rate of reaction into current density (b) Converting potential of a reaction into Gibbs free energy (c) Faraday constant ( in C, and Ah) (d) Capacitor: Non-faradic current (e) Metal-solution interface (f) Galvanic potential (g) Electrochemical series (h) Galvanic and electrolytic cells (i) Nernst equation
Voltage loss (overpotential) and Kinetics (a) Overpotential (activation, ohmic and concentration) (b) Rate law treatment to obtain Butler Volmer Kinetics (c) Tafel kinetics (d) Faraday’s laws and coulombic efficiency
Battery Materials (a) Primary and secondary batteries (b) Li/Li-ion battery (c) Anode materials (d) Cathode materials (e) Electrolytes (Non-aqueous) (f) Solid electrolyte interface (g) Cathode electrolyte interface (h) Energy Storage Mechanism (Intercalation, conversion and alloying) (i) Irreversible capacity loss (j) Theoretical Capacity (k) Volume strain (l) Zero strain materials (m) Solid state conductors (n) Superionic conductors (o) Na-ion battery materials
Electrochemical Techniques (a) Cyclic voltammetry (b) Chrono amperometry (c) Chrono potentiometry (d) Differential pulse voltammetry (e) Galvanostatic charge-discharge (f) dQ/dV vs. Capacity plot (g) Impedance spectroscopy, a non-destructive technique (h) Galvanostatic intermittent titration (i) Symmetric cell for critical current density analysis (j) Li+ transport number calculation
This module focusses on cell technologies that are employed in EVs today in India and globally. It provides a perspective from the automakers' (application) point of view: the battery technology selection criteria, implementation into the vehicles, and the challenges they face in ensuring safe and trouble-free experience for the customers, and the tools/processes they commonly use. It also describes the battery ecosystem in India and identifies imperatives for successful EV adoption, calling out indigenous cell manufacturing as a critical need.
Dr. Raghunathan, Professor of Practice at IIT Madras
Learning outcomes of this module:
Application of the Module:
